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TBH all I really know is that mixing colored light on a screen is not the same thing as mixing pigments. If you "mix" red and green in the MSPaint color selection wheel you get yellow, if you mix actual red and green paint IRL, you get poop. I know that simpler apps like Gimp don't correctly mix colors or create gradients, but Photoshop has a toggle to change how it works. If you create materials for printing you're supposed to work in CMYK. That's basically it.